Het breekt slechts langzaam af en kan zich opstapelen in de voedselketen, waarbij de concentratie zo hoog kan worden dat er vergiftigingsverschijnselen optreden. Technisch endosulfan is een mengsel van twee stereo-isomeren, alfa- en bèta-endosulfan. Numerous in vitro studies have documented its potential to disrupt hormones and animal studies have demonstrated its reproductive and developmental toxicity, especially among males. 27306-78-1 Formulations 35%EC ,95%TC Specifications CAS No. Endosulfan became a highly controversial agrichemical due to its acute toxicity, potential for bioaccumulation, and role as an endocrine disruptor. Levels of endosulfan residues on food in the U.S. Interim report on endosulfan submitted by expert committee to the Supreme Court of India, Aug 4, 2011, Weeping wombs of Kasaragod Tehelka Magazine, Vol 8, Issue 18, Dated 07 May 2011, Octamethylene-bis(5-dimethylcarbamoxyisoquinolinium bromide), Adrenosterone (11-ketoandrostenedione, 11-oxoandrostenedione), DHEA (androstenolone, prasterone; 5-DHEA), 7α-Methyl-19-norandrostenedione (MENT dione, trestione), 11β-Methyl-19-nortestosterone dodecylcarbonate, Normethandrone (methylestrenolone, normethisterone), Oxabolone cipionate (oxabolone cypionate), Methylclostebol (chloromethyltestosterone), Andarine (acetamidoxolutamide, androxolutamide, GTx-007, S-4), Enobosarm (ostarine, MK-2866, GTx-024, S-22), 3-Methyl-19-methyleneandrosta-3,5-dien-17β-ol, 10β,17β-Dihydroxyestra-1,4-dien-3-one (DHED), 16β,17α-Epiestriol (16β-hydroxy-17α-estradiol), 17α-Epiestriol (16α-hydroxy-17α-estradiol), Epiestriol (16β-epiestriol, 16β-hydroxy-17β-estradiol), Fosfestrol (diethylstilbestrol diphosphate), Furostilbestrol (diethylstilbestrol difuroate), Triphenylmethylethylene (triphenylpropene), https://en.wikipedia.org/w/index.php?title=Endosulfan&oldid=998119804, Persistent organic pollutants under the Stockholm Convention, Articles with dead external links from October 2010, Articles with dead external links from September 2010, Articles with dead external links from June 2016, Articles with dead external links from September 2017, Articles with permanently dead external links, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, 70 to 100 °C (158 to 212 °F; 343 to 373 K), 2000: Home and garden use in the United States was terminated by agreement with the, 2007: International steps were taken to restrict the use and trade of endosulfan. [46] Environmentally relevant doses of endosulfan equal to the EPA's safe dose of 0.006 mg/kg/day have been found to affect gene expression in female rats similarly to the effects of estrogen. Het heeft een kenmerkende geur als van terpentijn. [7] It has been used extensively on cotton, potatoes, tomatoes, and apples according to the EPA. Overall, this will lead to its elimination from the global markets. BHD. The statement adds, "However, given the fact that the endosulfan market is quite small and the cost of developing and submitting additional data high, we have decided to voluntarily negotiate an agreement with EPA that provides growers with an adequate time frame to find alternatives for the damaging insect pests currently controlled by endosulfan." Omdat niet kan gewaarborgd worden dat endosulfan op een veilige manier kan toegepast worden, heeft de Europese Commissie in 2005 een beschikking genomen om endosulfan te verbieden. Join Free For Buyer. [86] The Department of Health of the Philippines has temporarily banned the consumption of fish caught in the area. Endosulfan products are not registered for home garden use. Melting point 208-210°C. The apex court said the ban would remain effective for eight weeks during which an expert committee headed by DG, ICMR, will give an interim report to the court about the harmful effect of the widely used pesticide. "[50] Increased incidences of cryptorchidism have been observed in other studies of endosulfan exposed populations. Endosulfan has no residential uses. [14], Theo Colborn, an expert on endocrine disruption, lists endosulfan as a known endocrine disruptor,[44] and both the EPA and the Agency for Toxic Substances and Disease Registry consider endosulfan to be a potential endocrine disruptor. De introductie van de zwavelbrug vindt plaats via reactie met thionylchloride, waarbij endosulfan ontstaat. S4N 6C2 Telephone : 1-888-AVENTIS (1-888-283-6847) PRECAUTIONS: Bij de eigenschappen van endosulfan wordt melding gemaakt van een α- en een β-isomeer. [81] KM Sreekumar of the Padannakkad College of Agriculture in Kasargod and Prathapan KD of the Kerala Agricultural University in a paper claim that the extensive spread of diseases in the area cannot be solely attributed to the use of Endosulfan and criticised the CSE for inflating the level of endosulfan reported in the blood. The two isomers, endo and exo, are known popularly as I and II. Afbraakproducten van endosulfan zijn onder meer endosulfandiol en endosulfansulfaat, dat even giftig is als endosulfan. product that are covered by the Worker Protection Standard. The Pollution Control Board of the Government of Kerala, prohibited the use of endosulfan in the state of Kerala on 10 November 2010. World Services - Offering Endosulfan Insecticide, Keetnashak, कीटनाशक in Chennai, Tamil Nadu. [87] Endosulfan is classified as a "Severe Marine Pollutant" by the International Maritime Dangerous Goods Code.[20]. Bij zware gevallen kan bewusteloosheid en dood volgen. Via een diels-alderreactie ontstaat het gechloreerd derivaat van norborneen. In California, endosulfan contamination from the San Joaquin Valley has been implicated in the extirpation of the mountain yellow-legged frog from parts of the nearby Sierra Nevada. [69][70], The Karnataka government also banned the use of endosulfan with immediate effect. In fact, I have already made representation to the Prime Minister and concerned Union Ministers of health and environment demanding immediate withdrawal of the report," as reported by The Economic Times and Outlook India [72][73], Mrs. Vibhavari Dave, local leader and Member of Legislative Assembly (MLA), from Bhavnagar, Gujarat, voiced her concerns on the impact of ban of endosulfan on families and workers of Bhavnagar. The committee noted that the WHO, FAO, IARC and US EPA have indicated that endosulfan is not carcinogenic, not teratogenic, not mutagenic and not genotoxic. An organochlorine insecticide first registered in the 1950s, endosulfan can be used on a variety of vegetables and fruits, on cotton, and on ornamental plants. De stof kan bij kortstondige blootstelling effecten hebben op het centrale zenuwstelsel en het bloed. Docket ID No. De tekst is beschikbaar onder de licentie. Endosulfan was the only pesticide applied to cashew plantations in the villages for 20 years, and had contaminated the village environment. [56] Endosulfan has been found in remote locations such as the Arctic Ocean, as well as in the Antarctic atmosphere. In Nederland was het gebruik van endosulfan reeds eerder verboden. It is primarily used as an insecticide in agriculture & it is also used as a wood preservative. [1] Toelatingen voor gewasbeschermingsmiddelen die endosulfan bevatten moesten uiterlijk op 1 juni 2006 ingetrokken worden. [77] Indian Union Minister of Agriculture Sharad Pawar has ruled out implementing a similar ban at the national level despite the fact that endosulfan has banned in 63 countries, including the European Union, Australia, and New Zealand. Product Directory Endosulfan exists as two (α and β) isomers that can be metabolized to endosulfan sulfate and endosulfan diol. Endosulfan is a broad spectrum contact insecticide and acaricide registered for use on a wide variety of vegetables, fruits, cereal grains, and cotton, as well as ornamental shrubs, trees, vines, and ornamentals for use in commercial agricultural settings. Endosulfan is an insecticide to protect cotton, sugarcane, and vegetable crops. Er zijn gevallen beschreven waarbij een dosis van niet meer dan 35 mg/kg bij mensen de dood tot gevolg heeft. I'm in complete agreement with what the workers have to say on this. THIS PRODUCT IS TOXIC TO BEES AND SHOULD NOT BE APPLIED Endosulfan 350g/L Ec of Insecticide Pesticide & Acaricide picture from Sino Agro-Chemical Industry Ltd. view photo of Dimethoate, Emamectin Benzoate, Fenpyroximate.Contact China Suppliers for More Products and Price. Product Name: endosulfan 350g/L EC 95%TC: CAS NO. Blootstelling aan een hoge dosis, 35 mg/kg (2,8 gram voor iemand van 80 kg), kan een dodelijke afloop hebben. The EPA concluded, "[b]ased on environmental fate laboratory studies, terrestrial field dissipation studies, available models, monitoring studies, and published literature, it can be concluded that endosulfan is a very persistent chemical which may stay in the environment for lengthy periods of time, particularly in acid media." [90] In Florida, levels of contamination the Everglades and Biscayne Bay are high enough to pose a threat to some aquatic organisms. However some scientists have called this study flawed. [101] Citing New Zealand's ban, the Australian Greens called for "zero tolerance" of endosulfan residue on food. Endosulfan was banned in New Zealand by the Environmental Risk Management Authority effective January 2009[33] after a concerted campaign by environmental groups and the Green Party. [29] In June 2010, the EPA announced it was negotiating a phaseout of all uses with the sole US manufacturer, Makhteshim Agan, and a complete ban on the compound. Menu Sign In. "[60] In May 2011, the Stockholm Convention committee approved the recommendation for elimination of production and use of endosulfan and its isomers worldwide. The committee constituted for the study also included former Deputy Director of NIOH, Ahmadabad. Birth defects of the male reproductive system, including cryptorchidism, were also more prevalent in the study group. [48] A 2009 assessment concluded the endocrine disruption in rats occurs only at endosulfan doses that cause neurotoxicity. Search, rescue, and salvage efforts were suspended when the endosulfan shipment was discovered, and blood samples from divers at the scene were sent to Malaysia for analysis. Endosulfan lost bijna niet op in water, maar wordt geadsorbeerd aan (water)bodemdeeltjes. Endosulfan is an off-patent organochlorine insecticide and acaricide that is being phased out globally. [61], Although classified as a yellow label (highly toxic) pesticide by the Central Insecticides Board, India is one of the largest producers[62] and the largest consumer of endosulfan in the world. Beschikking van de Commissie van 2 december 2005 betreffende de niet-opneming van endosulfan in bijlage I bij Richtlijn 91/414/EEG van de Raad en de intrekking van de toelating voor gewasbeschermingsmiddelen die deze werkzame stof bevatten, https://nl.wikipedia.org/w/index.php?title=Endosulfan&oldid=51762600, Wikipedia:Wel afbeelding lokaal en geen op Wikidata, Creative Commons Naamsvermelding/Gelijk delen, 1,2,3,4,7,7-hexachloor-8,9,10-trinorborn-2-een-5,6-yleendimethylsulfiet. [7], An official statement by Makhteshim Agan of North America (MANA) states, "From a scientific standpoint, MANA continues to disagree fundamentally with EPA's conclusions regarding endosulfan and believes that key uses are still eligible for re-registration." [74][75] In a 2016 study[55] by the Department of Biochemistry, Indian Institute of Science, Bangalore published in Carcinogenesis, endosulfan was found to induce reactive oxygen species (ROS) in a concentration and time-dependent manner leading to double-stranded breaks in the DNA and also found to favour subsequent erroneous DNA repair. Endosulfan: Request for Additional Information on Usage and Availability of Alternatives, PETITION TO BAN ENDOSULFAN AND REVOKE ALL TOLERANCES AND COMMENTS ON THE ENDOSULFAN UPDATED RISK ASSESSMENT (OPP-2002-0262-0067) BY THE NATURAL RESOURCES DEFENSE COUNCIL, "Open letter to Stephen Johnson, Administrator, U.S. Environmental Protection Agency: ban endosulfan", "Group sues to ban DDT-related pesticide", POPRC-4 — Summary and Analysis, 20 October 2008, "Endosulfan and other chemicals being assessed for listing under the Stockholm Convention", "UN chemical body recommends elimination of the toxic pesticide endosulfan", "Australia finally bans endosulfan. Het wordt ook gebruikt als houtbeschermingsmiddel. [21][65] This flared up the protest,[66][67][68] and while India still maintained its stance, the global conference decided on a global ban, for which India asked a remission for 10 years. This product acts as a poison and is used for controlling sucking and chewing insects like bollworm, aphids, stem borer, thrips etc. Handelsnamen zijn onder andere: … Briefing presspersons after the State Cabinet meeting, Minister for Higher Education V.S. Juist in de katoenteelt speelt endosulfan vanwege zijn bre-de werkingsspectrum tegen insecten een belangrijke rol omdat katoen uiterst vat- baar is voor aantasting door insecten en ziekteverwekkers. She was a part of the delegation with Bhavnagar MP, Rajendra Singh Rana, which submitted a memorandum to the district collector's office to withdraw the NIOH report calling for ban of endosulfan. Endosulfan is an organochlorine insecticide and acaracide used to control a broad range of insect and arthropod pests on a wide variety of food, feed and ornamental crops. United States Environmental Protection Agency, http://www.hc-sc.gc.ca/cps-spc/pubs/pest/_decisions/rev2011-01/index-eng.php, "Endosulfan: Canada's submission of information specified in Annex E of", "Florida Crop/Pest Management Profiles: Tomatoes. Because of its threats to human health and the environment, a global ban on the manufacture and use o… EPA-HQ-OPP-2008-0615-0041.1", "Endosulfan Updated Risk Assessments, Notice of Availability, and Solicitation of Usage Information", "Petitions to Revoke All Tolerances Established for Endosulfan; Notice of Availability", "MANA And EPA Agree To Voluntary Plan On Endosulfan", "MANA, EPA Agree To Voluntary Plan On Endosulfan", "Registration of endosulfan cancelled in Australia", "Regulator finally acts to ban endosulfan", "Australia refuses to join ban on pesticide", Taiwan Academics slam end of pesticide ban for U.S. fruit, "Agrotóxico endosulfan será banido no Brasil em 2013; demora é criticada", CDC - NIOSH Pocket Guide to Chemical Hazards, 2009 Environmental Justice Foundation report detailing impacts of Endosulfan, highlighting why it should be banned globally, Resources on Endosulfan, India Environment Portal. It may cause convulsions. Het wordt ook gebruikt als houtbeschermingsmiddel. Its effect remains for a short span of time and does not harm the predators of the beneficial insects. [49], Endosulfan is not listed as known, probable, or possible carcinogen by the EPA, IARC, or other agencies. [40][45] Endosulfan has shown to affect crustacean molt cycles, which are important biological and endocrine-controlled physiological processes essential for the crustacean growth and reproduction. Minister for Energy, and Food and Civil Supplies Shobha Karandlaje, who has been spearheading a movement seeking a ban on endosulfan, said, "I am grateful to Chief Minister B.S. Endosulfan is subject to long-range atmospheric transport, i.e. A wide variety of endosulfan … [84] On January 10, 2017, The Supreme Court ordered the State Governments to release the remaining undisbursed payment of compensation quantified (Rupees Five lakhs each) to all the affected persons within three months.[85]. 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